European Journal of Organic Chemistry

Iron??Catalyzed One??Pot Oxidative Esterification of Aldehydes

XF Wu, C Darcel

文献索引：Wu, Xiao-Feng; Darcel, Christophe European Journal of Organic Chemistry, 2009 , # 8 p. 1144 - 1147

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被引用次数: 44

摘要

Abstract A highly efficient, mild, and simple protocol for Fe (ClO 4) 3· xH 2 O-catalyzed oxidative esterification of aldehydes was developed. Several aromatic and aliphatic aldehydes reacted with simple primary and secondary alcohols, used as the solvent, smoothly in the presence of an iron salt catalyst (10 mol-%) and hydroperoxide (4 equiv.) as an oxidant to generate the corresponding esters in good to excellent yields.(© Wiley-VCH ...