An aluminum ate base: Its design, structure, function, and reaction mechanism
H Naka, M Uchiyama, Y Matsumoto…
文献索引：Naka, Hiroshi; Uchiyama, Masanobu; Matsumoto, Yotaro; Wheatley, Andrew E. H.; McPartlin, Mary; Morey, James V.; Kondo, Yoshinori Journal of the American Chemical Society, 2007 , vol. 129, # 7 p. 1921 - 1930
An aluminum ate base, i-Bu3Al (TMP) Li, has been designed and developed for regio-and chemoselective direct generation of functionalized aromatic aluminum compounds. Direct alumination followed by electrophilic trapping with I2, Cu/Pd-catalyzed CC bond formation, or direct oxidation with molecular O2 proved to be a powerful tool for the preparation of 1, 2- or 1, 2, 3-multisubstituted aromatic compounds. This deprotonative alumination using i- ...
