Journal of Organic Chemistry 2005-09-30

Copper-catalyzed arylation of amines using diphenyl pyrrolidine-2-phosphonate as the new ligand.

Honghua Rao, Hua Fu, Yuyang Jiang, Yufen Zhao

文献索引：J. Org. Chem. 70(20) , 8107-9, (2005)

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摘要

[Chemical reaction: See text] We have developed a general, efficient, and inexpensive catalyst system for arylation of amines by using 10 mol % of CuI as the copper source, 20 mol % of diphenyl pyrrolidine-2-phosphonate (DPP) as the ligand, K3PO4 as the base, and DMF containing 2% water (v/v) as the solvent.