Tetrahedron

First synthesis of nitro-substituted 2, 2-diphenyl-2H-1-benzopyrans via the ipso-nitration reaction

L Bougdid, A Heynderickx, S Delbaere, C Moustrou

文献索引：Bougdid, Lahoussine; Heynderickx, Arnault; Delbaere, Stephanie; Moustrou, Corinne Tetrahedron, 2007 , vol. 63, # 34 p. 8242 - 8249

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被引用次数: 10

摘要

The first synthesis of a series of nitro-substituted 2, 2-diphenyl-2H-1-benzopyrans is reported. Our synthetic approach is based on a linear synthesis in two steps from appropriate brominated 2, 2-diphenyl-2H-1-benzopyrans 12–17, which requires the preliminary preparation of bromophenols 7–11. These latter were easily obtained by the reaction of phenols 1–5 with a mild and selective brominating agent tetrabutylammonium ...