Angewandte Chemie. International edition in English 2015-01-07

A rod-packing microporous hydrogen-bonded organic framework for highly selective separation of C2H2/CO2 at room temperature.

Peng Li, Yabing He, Yunfeng Zhao, Linhong Weng, Hailong Wang, Rajamani Krishna, Hui Wu, Wei Zhou, Michael O'Keeffe, Yu Han, Banglin Chen

文献索引：Angew. Chem. Int. Ed. Engl. 54(2) , 574-7, (2015)

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摘要

Self-assembly of a trigonal building subunit with diaminotriazines (DAT) functional groups leads to a unique rod-packing 3D microporous hydrogen-bonded organic framework (HOF-3). This material shows permanent porosity and demonstrates highly selective separation of C2H2/CO2 at ambient temperature and pressure.© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.