Journal of the Chemical Society, Perkin Transactions 1

Reaction of methyl diazoacetate with aldehydes, amines, thiols, alcohols and acids over transition metal-exchanged clays

JM Mohan

文献索引：Phukan, Prodeep; Mohan, Jakkam Madan; Sudalai, Arumugam Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 24 p. 3685 - 3689

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被引用次数: 17

摘要

Metal-exchanged clays (M= Rh and Cu) catalyze effectively the reaction of methyl diazoacetate with various aldehydes, affording the corresponding β-keto esters in high yields. They have also been effective in the decomposition of methyl diazoacetate to form metallocarbenes which, in turn, successfully insert into X–H (X= N, O, S, CO2) bonds of a variety of amines, aldehydes, thiols and acids, thereby producing the corresponding ...