Nanoscale Fe2O3-based catalysts for selective hydrogenation of nitroarenes to anilines

…, J Rabeah, H Huan, V Schünemann, A Brückner…

文献索引：Jagadeesh, Rajenahally V.; Surkus, Annette-Enrica; Junge, Henrik; Pohl, Marga-Martina; Radnik, Joerg; Rabeah, Jabor; Huan, Heming; Schunemann, Volker; Brueckner, Angelika; Beller, Matthias Science, 2013 , vol. 342, # 6162 p. 1073 - 1076

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被引用次数: 176

摘要

Abstract Production of anilines—key intermediates for the fine chemical, agrochemical, and pharmaceutical industries—relies on precious metal catalysts that selectively hydrogenate aryl nitro groups in the presence of other easily reducible functionalities. Herein, we report convenient and stable iron oxide (Fe 2 O 3)–based catalysts as a more earth-abundant alternative for this transformation. Pyrolysis of iron-phenanthroline complexes on carbon ...