前往化源商城

Carbohydrate Research 2003-02-14

Zinc triflate-benzoyl bromide: a versatile reagent for the conversion of ether into benzoate protecting groups and ether glycosides into glycosyl bromides.

Tülay Polat, Robert J Linhardt

文献索引:Carbohydr. Res. 338(5) , 447-9, (2003)

全文:HTML全文

摘要

A simple and efficient method is developed for the chemoselective one-pot conversion of ethers (benzyl, TBDMS and acetal) to the corresponding benzoates by zinc triflate-catalyzed deprotection and benzoylation by benzoyl bromide. In the same reaction, methyl or p-methoxyphenyl glycosides are converted into glycosyl bromides that are useful in glycosylation reactions.

相关化合物

结构式 名称/CAS号 全部文献
苄氧基溴 结构式 苄氧基溴
CAS:618-32-6