The Journal of Organic Chemistry

Hydroxylation of nitroarenes with alkyl hydroperoxide anions via vicarious nucleophilic substitution of hydrogen

M Makosza, K Sienkiewicz

文献索引：Makosza, Mieczyslaw; Sienkiewicz, Krzysztof Journal of Organic Chemistry, 1998 , vol. 63, # 13 p. 4199 - 4208

被引用次数: 61

摘要

Carbo-and heterocyclic nitroarenes react with anions of tert-butyl and cumyl hydroperoxides in the presence of strong bases to form substituted o-and p-nitrophenols. The reaction usually proceeds in high yields and is of practical value as a method of synthesis and manufacturing of nitrophenols. Orientation of the hydroxylation can be controlled to a substantial extent by selection of the proper conditions. Basic mechanistic features of this ...

~79%

查看详情

~78%

查看详情

2243-80-3

3-硝基二苯甲酮

~76%

查看详情

~23%

查看详情

~84%

查看详情

~18%

查看详情

~83%

查看详情

~11%

查看详情

~66%

查看详情

~65%

查看详情

~63%

查看详情

~86%

查看详情

~88%

查看详情

~51%

查看详情

~78%

查看详情

~86%

查看详情

~83%

查看详情

~89%

查看详情

~27%

查看详情

~80%

查看详情

Oxalylchloride/DMF as an Efficient Reagent for Nitration of ...

[Kumar, M. Satish; Reddy, K. Rajendar; Rajanna; Venkanna; Krishnaiah Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2013 , vol. 43, # 8 p. 977 - 983]

Palladium-catalyzed cleavage of O/N-propargyl protecting gro...

[Pal, Manojit; Parasuraman, Karuppasamy; Yeleswarapu, Koteswar Rao Organic Letters, 2003 , vol. 5, # 3 p. 349 - 352]

Reactivity of nitrite with 2-chlorophenol, t-butyl phenol an...

[Bulletin de la Societe Chimique de France, , vol. 133, # 10 p. 973 - 977]

Hydroxylation of nitroarenes with alkyl hydroperoxide anions...

[Journal of Organic Chemistry, , vol. 63, # 13 p. 4199 - 4208]