Properties of bis (trifluoroacetoxy) borane as a reducing agent of organic compounds

BE Maryanoff, DF McComsey…

文献索引：Maryanoff, Bruce E.; McComsey, David F.; Nortey, Samuel O. Journal of Organic Chemistry, 1981 , vol. 46, # 2 p. 355 - 360

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被引用次数: 47

摘要

Reactions of bis (trifluoroacetoxy) borane-THF (1) with compounds containing representative organic functional groups were studied to determine the usefulness of 1 as a selective reducing agent. Reducible functionalities were indoles, ketones, aldehydes, imines, and compounds that readily generate carbocations in trifluoroacetic acid. Many functionalities were inert to 1. Epoxides and ortho esters suffered decomposition under the ...