Microwave-assisted carbonylation and cyclocarbonylation of aryl iodides under ligand free heterogeneous catalysis

J Salvadori, E Balducci, S Zaza, E Petricci…

文献索引：Salvadori, Jessica; Balducci, Evita; Zaza, Silvia; Petricci, Elena; Taddei, Maurizio Journal of Organic Chemistry, 2010 , vol. 75, # 6 p. 1841 - 1847

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被引用次数: 83

摘要

Carbonylation reaction is a very effective transformation for the synthesis of esters, amides, and heterocyclic compounds. Heterogeneous catalyzed carbonylation reactions can be carried out using the association of Pd/C and microwave dielectric heating. Alkoxy carbonylation can be performed with stoichiometric amounts of different primary and secondary alcohols in DMF in the presence of DBU as the base. Analogously, ...