Tetrahedron letters

Intermolecular reductive cross coupling of carbonyl compounds with nitriles induced by low-valent titanium

J Gao, M Hu, J Chen, S Yuan, W Chen

文献索引：Gao, Ju; Hu, Ming-yang; Chen, Jian-xie; Yuan, Su; Chen, Wei-xing Tetrahedron Letters, 1993 , vol. 34, # 10 p. 1617 - 1620

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被引用次数: 10

摘要

Ju Gao, Ming-yang Hu, Jian-xie Chen, Su Yuan, Wei-xing Chen ● Department of Chemistry, Nanjing University, Nanjing, 210008, China ... Abstract: Intermolecular cross coupling of carbonyl compounds with nitriles promoted by TiC!l,-Zn leads to ketones. ... Carbonyl compounds undergo intermolecular reductive coupling reaction to yield olefins on treatment with low-valent titanium reagent.' The reaction is usually limited to the preparation of symmetrical olafins from ...