Environmental Science & Technology 2012-02-07

Fabrication of CaO-based sorbents for CO₂ capture by a mixing method.

Changlei Qin, Wenqiang Liu, Hui An, Junjun Yin, Bo Feng

文献索引：Environ. Sci. Technol. 46(3) , 1932-9, (2012)

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摘要

Three types of sorbent were fabricated using various calcium and support precursors via a simple mixing method, in order to develop highly effective, durable, and cheap CaO-based sorbents suitable for CO(2) capture. The sorption performance and morphology of the sorbents were measured in a thermogravimetric analyzer and a scanning electron microscopy, respectively. The experimental results indicate that cement is a promising low-cost support precursor for contributing to the enhancement of cyclic CO(2) sorption capacity, especially when organometallic calcium precursors were used. A sorbent (with 75% CaO content) made from calcium l-lactate hydrate and cement showed the highest CO(2) sorption capacity of 0.36 g of CO(2)/g of sorbent and its capacity decreased only slightly after 70 cycles of carbonation and calcination.