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Journal of the American Chemical Society 2006-09-13

Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis.

Shuichi Yanagisawa, Tomoko Sudo, Ryoji Noyori, Kenichiro Itami

文献索引:J. Am. Chem. Soc. 128 , 11748, (2006)

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摘要

A new method for the catalytic C-H arylation of heteroarenes and arenes that manifests high activity paired with reasonably broad scope was developed. Under the catalytic influence of RhCl(CO){P[OCH(CF3)2]3}2 and Ag2CO3, the direct C-H arylation of heteroarenes/arenes with aryl/heteroaryl iodides took place to afford a range of biaryls in good to excellent yields with high regioselectivity. Thiophenes, furans, pyrroles, indoles, and alkoxybenzenes are applicable in this arylation protocol.

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