The Journal of Organic Chemistry

Interaction of cyclopropane with platinum-metal chlorides under carbon monoxide pressure in benzene

TH Johnson, TF Baldwin

文献索引：Johnson, Thomas J.; Baldwin, Thomas F. Journal of Organic Chemistry, 1980 , vol. 45, # 1 p. 140 - 142

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被引用次数: 8

摘要

Results We first reexamined the reaction of cyclopropane with palladium chloride in benzene under 100 atm of carbon monoxide at 90" C. We found that the ratio of chlorobutyrates (73%) to n-propylbenzene (27% 1 was similar to that reported earlier. 3 While the formation and ratio of these products was not too dependent upon carbon monoxide pressure and temperature, we did find that the ratio of products was very ...