Organometallics

Carbamoyl (Carboxamido) Complexes as Precursors for Metallaoxetene, Isonitrile, and Aminomethylidyne Complexes of Iron

S Anderson, AF Hill, YT Ng

文献索引：Anderson, Stephen; Hill, Anthony F.; Ng, Ying Thong Organometallics, 2000 , vol. 19, # 1 p. 15 - 21

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被引用次数: 14

摘要

The bidentate carbamoyl complex [Fe (η2-OCNiPr2)(CF3)(CO) 2 (PPh3)] serves as a precursor to aminomethylidyne, ferraoxetene, difluorocarbene, and isonitrile complexes via unusual transformations of the carbamoyl and trifluoromethyl ligands.