Reductive elimination of aryl carboxylates from acyl (aryloxy) nickel (II) and-palladium (II) complexes

…, Y Akai, K Tanaka, T Yamamoto, A Yamamoto

文献索引：Komiya, Sanshiro; Akai, Yasushi; Tanaka, Kohkichi; Yamamoto, Takakazu; Yamamoto, Akio Organometallics, 1985 , vol. 4, p. 1130 - 1136

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被引用次数: 90

摘要

Acyl@-cyanophenoxy) nickel (II) and-palladium (II) complexes, M (COR)(OCeH4-p-CN) L2 (M= Ni, Pd; Lz= bpy,(PEtJ2), have been prepared by insertion reactions of CO into the metal- carbon bonds of the corresponding methylnickel (I1) and-palladium (II) complexes. Addition of n-acids such as CO, maleic anhydride, and acrylonitrile selectively induces reductive elimination of p-cyanophenyl acetate from acylnickel (II) complexes, whereas thermolysis ...