Carbene in rigid matrix. XI. Temperature and matrix effect on phenylcarbene processes in ether and amine.

H Tomioka, S Suzuki, Y Izawa

文献索引：Tomioka, Hideo; Suzuki, Shinji; Izawa, Yasuji Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 2 p. 492 - 495

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被引用次数: 8

摘要

Product distributions from reactions of phenylcarbene with diethyl or diisopropyl ether or diethylamine were found to be highly dependent on reaction temperature. As temperature decreases, the C–O displacement reaction and N–H insertion are decreased. Concomitantly, primary C–H insertion products markedly increase especially at lower matrix temperatures.