The Condensation Reactions of Bivalent Sulfur Compounds-Copper (II) Complexes with Nucleophiles

T Mukaiyama, K Narasaka, K Maekawa…

文献索引：Mukaiyama,T. et al. Bulletin of the Chemical Society of Japan, 1970 , vol. 43, p. 2549 - 2553

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被引用次数: 14

摘要

It was found that the bivalent sulfur compounds such as benzaldehyde diethylmercaptal, benzophenone diethylmercaptole, ethyl orthotrithioformate and benzyl methylsulfide, react with copper (II) salts of 1, 3-dicarbonyl compounds, active methylene compounds or anisole, in the presence of cupric chloride, to give condensation or substitution products in good yields accompanied with carbon-sulfur bond cleavage. On the other hand, in the absence ...