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t??Butyl hydroperoxide oxidative dealkylation of hydroquinone ethers to 1, 4??quinones

H Wójtowicz, J Młochowski, L Syper…

文献索引:Wojtowicz, Halina; Mlochowski, Jacek; Syper, Ludwik; Yadav, Hardeo Synthetic Communications, 2006 , vol. 36, # 14 p. 1991 - 2000

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被引用次数: 14

摘要

Abstract Various organoselenium compounds (diselenides, benzisoselenazol??3 (2H)??ones, and 1, 3, 2??thiaselenazolones) are effective catalysts for oxidative dealkylation of hydroquinone ethers with t??butyl hydroperoxide to 1, 4??quinones. The reactions is most efficient when t??butyl hydroperoxide in the presence of poly (bis??1, 2??phenyl) diselenide is used as an oxidizing agent. In this way 1, 4??benzo and 1, 4??naphthoquinones are ...