Chemistry Letters

Intramolecular alkylation of vinylgermanes and iododegermylation of 1-cycloalkenylgermanes

H Oda, K Oshima, H Nozaki

文献索引：Oda, Hiroji; Oshima, Koichiro; Nozaki, Hitosi Chemistry Letters, 1985 , p. 53 - 56

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被引用次数: 7

摘要

Whereas 2-methyl-2, 3-epoxy-6-triethylgermyl-6-tridecene gave the expected alkylidenecyclopentanol upon treatment with TiCl 4, 5-triethylgermyl-5-dodecenal dimethyl acetal provided the unexpected cyclohexene derivative. Transformation of 1- triethylgermylcycloalkenes into 1-iodocycloalkenes is also described.