Synthesis of supercritical carbon dioxide soluble perfluorinated dendrons for surface modification

CK Luscombe, S Proemmel, WTS Huck…

文献索引：Luscombe, Christine K.; Proemmel, Steffen; Huck, Wilhelm T. S.; Holmes, Andrew B.; Fukushima, Hitoshi Journal of Organic Chemistry, 2007 , vol. 72, # 15 p. 5505 - 5513

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被引用次数: 14

摘要

The rational design, synthesis, and characterization of a series of novel perfluorinated dendrons 14a, b, 25a, b, 26a, b, and 18 are described. The dendrimers were designed to have a thiol at the focal point for attachment to a gold surface to enable the fabrication of self- assembled monolayers (SAMs). Perfluorinated tails were attached to the periphery to provide solubility in supercritical carbon dioxide, and to increase the hydrophobicity and ...