Acetylacetone and malononitrile were coupled with diazotized arylamines to give arylazoacetyl-acetones and arylazomalononitriles. When refluxed with 3-hydrazino-4, 5- diphenyl-1H-pyrazolo-[3, 4-c] pyridazine in the presence of ethanol/HCl, they yielded the