Preparation and reactions of lithium derivatives of trifluoropropene and trifluoropropyne

FG Drakesmith, OJ Stewart…

文献索引：Drakesmith,F.G. et al. Journal of Organic Chemistry, 1968 , vol. 33, # 1 p. 280 - 285

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被引用次数: 145

摘要

3, 3, 3-Tritluoroisopropenyllithium has been prepared by exchange metallation between 3, 3, 3-trifluoroisopropenyl bromide and an alkyllithium reagent. The unsaturated fluoroorganic lithium compound is unstable even below-90" decomposing by elimination of lithium ...