Journal of the American Chemical Society

A new method for the alkylation of ketones and aldehydes: the C-alkylation of the Magnesium salts of N-substituted imines

G Stork, SR Dowd

文献索引：Stork,G.; Dowd,S.R. Journal of the American Chemical Society, 1963 , vol. 85, p. 2178 - 2180

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被引用次数: 294

摘要

I1 chromatography showed to be pure (2, 4-dinitrophenylhydrazone, mp 150-152'; reported6 mp 154-155'). The yield of distilled product? based on the imine used was 80%. In similar fashion, the cyclohexylimine from cyclohexanone gave with butyl iodide 78% of 2- butylcyclohexanone; with butyl toluene sulfonate, 80% of 2-butylcyclohexanone; with allyl bromide,