Organometallics

Organoboranes. 31. A simple preparation of boronic esters from organolithium reagents and selected trialkoxyboranes

HC Brown, TE Cole

文献索引：Brown, Herbert C.; Cole, Thomas E. Organometallics, 1983 , vol. 2, p. 1316 - 1319

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被引用次数: 245

摘要

The reaction of methyllithium with trimethoxyborane at-78 “C in ethyl ether yields a mixture of methylated boranes and their corresponding “ate” complexes. We have found that under the same conditions triisopropoxyborane reacts cleanly with methyllithium to form the lithium methyltriisopropoxyborate complex. Protonation of this complex with anhydrous hydrogen chloride quantitatively yields methyl diisopropoxyborane. This reaction of organolithium ...