前往化源商城

The Journal of Organic Chemistry

Radical pathways of coal dissolution in hydrogen donor media. 2.. beta. Scission and 1, 2 aryl migration reactions of radicals derived from methylindans and tetralin at …

JA Franz, DM Camaioni

文献索引:Franz, James A.; Camaioni, Donald M. Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5247 - 5255

全文:HTML全文

被引用次数: 43

摘要

The 1, 2 aryl migration and fragmentation reactions of 1-indanylmethyl (l), 2-tetralyl (2), 24ndanylmethyl (3), l-tetralyl (4), 2-methyl-l-indanyl (5), and l-methyl-2-indanyl (6) radicals were studied by flash vacuum pyrolysis of the tert-butyl perester precursors at 327-627 OC and torr. Radicals 1 and 2 are interconverted via a 1, 2 aryl migration which is readily reversible at all temperatures. This equilibrium is depleted by@ scission of 1 and ...

 相关合成线路

~%

查看详情

~9%

详细 查看详情

~22%

详细 查看详情

~34%

详细 查看详情

~15%

详细 查看详情

~27%

详细 查看详情

~29%

详细 查看详情

~8%

详细 查看详情

~25%

详细 查看详情

~10%

详细 查看详情

~17%

详细 查看详情

~13%

详细 查看详情

~%

查看详情

~%

查看详情

~7%

详细 查看详情

~6%

详细 查看详情

~4%

详细 查看详情