Hypervalent Iodine (III) Sulfonate Mediated Synthesis of α??Thiocynanatoketones in a Task??Specific Ionic Liquid [bmim] SCN

HY Huang, HM Wang, RS Hou…

文献索引：Huang, Hsin-Yu; Wang, Huey-Min; Hou, Rei-Sheu; Cheng, Hui-Ting; Chen, Ling-Ching Journal of the Chinese Chemical Society, 2008 , vol. 55, # 6 p. 1204 - 1207

全文：HTML全文

被引用次数: 7

摘要

Abstract The task-specific ionic liquid (TSIL) and 1-n-butyl-3-methylimidazolium thiocynanate,([bmim] SCN) were used as the medium as well as the reactant for the synthesis of α-thiocynanatoketones by the reaction with α-sulfonyloxy aryl ketones. Significant rate enhancements and improved yields have been observed.