Organic Letters 2006-09-14

Herrmann-Beller phosphapalladacycle-catalyzed addition of alkynes to norbornadienes.

Alphonse Tenaglia, Laurent Giordano, Gérard Buono

文献索引：Org. Lett. 8 , 4315, (2006)

摘要

Herrmann-Beller (H-B) phosphapalladacycle selectively catalyzed the addition of terminal alkynes across one double bond of norbornadiene to afford exo-5-alkynyl-bicyclo[2.2.1]hept-2-enes. The reaction shows general applicability to various functionalized alkynes and bicyclo[2.2.1]hepta-2,5-dienes. Insights into the mechanism of this reaction are discussed.

结构式	名称/CAS号	分子式	全部文献
	反式二-(m)-双[2-(二邻甲苯基膦)苄基]乙酸二钯(II) CAS:172418-32-5	C₄₆H₄₆O₄P₂Pd₂

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Louie, J.; Hartwig, J. F.
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Herrmann-Beller phosphapalladacycle-catalyzed addition of alkynes to norbornadienes.

摘要

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