Organic letters

A novel type of nucleophilic substitution reactions on nonactivated aromatic compounds and benzene itself with trimethylsiliconide anions

A Postigo, RA Rossi

文献索引：Organic letters, , vol. 3, # 8 p. 1197 - 1200

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被引用次数: 18

摘要

... Volume: Page: ... Organic Letters. ... The reaction of fluorobenzene with Me 3 Si - anion (1) in HMPA at room temperature surprisingly affords o- and p-fluorotrimethylsilylbenzenes (substitution of aromatic H for TMS, 76% yield) 7a and 7b and also 14% of ...