Journal of the American Chemical Society

Cyclopropanes from Allylic Chlorides via Hydroborination

MF Hawthorne

文献索引：Hawthorne,M.F. Journal of the American Chemical Society, 1960 , vol. 82, p. 1886 - 1888

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被引用次数: 30

摘要

Alkyl-and arylcyclopropanes were prepared from the corresponding@-alkyl or@-arylallyl chlorides. The use of the a-or the y-substituted isomers (or an equilibrium mixture of the two) would have led to the formation of a mixture of substituted cyclopropane and isomeric olefin. This situation imposed a limitation upon the usefulness of the