Tris (dialkylamino) sulfonium enolates. Synthesis, structure, and reactions

R Noyori, I Nishida, J Sakata

文献索引：Noyori, R.; Nishida, I.; Sakata, J. Journal of the American Chemical Society, 1983 , vol. 105, # 6 p. 1598 - 1608

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被引用次数: 213

摘要

Abstract: A mixture of an enol trimethylsilyl ether and a fluoride salt exists in a dynamic equilibrium with an enolate species and fluorotrimethylsilane. Evacuation of an equimolar mixture of an enol trimethylsilyl ether of benzyl methyl ketone and tris (diethy1amino) sulfonium (TAS) difluorotrimethylsiliconate produces fluorotrimethylsilane as the volatile fraction and the corresponding TAS enolate as air-sensitive crystals. The conductivity ...