Cleavage of silicon-nitrogen bonds by acid chlorides: an unusual synthetic route to amides

JR Bowser, PJ Williams, K Kurz

文献索引：Bowser, James R.; Williams, Pamela J.; Kurz, Kenneth Journal of Organic Chemistry, 1983 , vol. 48, # 22 p. 4111 - 4113

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被引用次数: 42

摘要

This reaction has been extensively used in organometallic synthesis;'however, the C-C1 bond of alkyl and aryl chlorides is generally inert toward silylamines. Early exceptions were observed by Anderson2 and by Pump and Wannagat, 3 who converted an acid halide into a silylsubstituted amide by this method (eq 2).

1735-00-8

N(三甲基甲硅烷基)乙胺

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