Tetrahedron

Halodeboronation of organotrifluoroborates using tetrabutylammonium tribromide or cesium triiodide

ML Yao, GW Kabalka, DW Blevins, MS Reddy, L Yong

文献索引：Yao, Min-Liang; Kabalka, George W.; Blevins, David W.; Reddy, Marepally Srinivasa; Yong, Li Tetrahedron, 2012 , vol. 68, # 19 p. 3738 - 3743

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被引用次数: 7

摘要

Halodeboronation of organotrifluoroborates using commercially available tetrabutylammonium tribromide (TBATB) or cesium triiodide in aqueous medium is reported. The mild, transition metal-free method has proven to be tolerant of a wide range of functional groups. High regio-and chemoselectivity are observed. Two synthetic routes to (Z)- dibromoalkenes from alkynes, through stereodefined (Z)-2-bromoalkenyltrifluoroborates ...