Diphenylphosphinophenolate: a ligand for the palladium-catalysed silylation of aryl halides activating simultaneously both palladium and silicon

E Shirakawa, T Kurahashi, H Yoshida…

文献索引：Shirakawa; Kurahashi; Yoshida; Hiyama Chemical Communications, 2000 , # 19 p. 1895 - 1896

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被引用次数: 4

摘要

Diphenylphosphinophenolate was found to be an effective ligand for the palladium- catalysed silylation of aryl halides, activating not only palladium but also silicon of a disilane, where aryl bromides and iodides having such substituents as methyl, methoxy, amino, ethoxycarbonyl, trifluoromethyl, formyl or phenyl are applicable to the reaction with hexamethyldisilane to give the corresponding trimethylsilylarenes.