Novel electrophilic species equivalent to. alpha.-keto cations. Reactions of 0, 0-diprotonated nitro olefins with benzenes yield arylmethyl ketones

K Okabe, T Ohwada, T Ohta…

文献索引：Okabe, Kazuaki; Ohwada, Tomohiko; Ohta, Toshiharu; Shudo, Koichi Journal of Organic Chemistry, 1989 , vol. 54, # 4 p. 733 - 734

全文：HTML全文

被引用次数: 27

摘要

Summary: The N, N-dihydroxyiminium carbenium ions formed by 0, O-diprotonation of nitro olefins in a strong acid, trifluoromethanesulfonic acid (TFSA), are discrete and novel dipositively charged species. The dications formed from a-substituted nitroethylenes are ...

详细

Palladium??Catalyzed Mono?螃窿?Arylation of Acetone with Aryl ...

[Ackermann, Lutz; Mehta, Vaibhav P. Chemistry - A European Journal, 2012 , vol. 18, # 33 p. 10230 - 10233]

Chemical, Kinetic, and Spectroscopic Evidence for the Reacti...

[Barcus, Robert L.; Wright, Bradford B.; Platz, Matthew S.; Scaiano, J. C. Tetrahedron Letters, 1983 , vol. 24, # 37 p. 3955 - 3958]

Syntheses of arylacetone and arylacetonitrile by Friedel-Cra...

[Tamura, Yasumitsu; Choi, Hong Dae; Mizutani, Masako; Ueda, Yuko; Ishibashi, Hiroyuki Chemical and Pharmaceutical Bulletin, 1982 , vol. 30, # 10 p. 3574 - 3579]

1-Naphthylcarbene: spectroscopy, kinetics, and mechanisms

[Barcus, R. L.; Hadel, L. M.; Johnston, L. J.; Platz, M. S.; Savino, T. G.; Scaiano, J. C. Journal of the American Chemical Society, 1986 , vol. 108, # 14 p. 3928 - 3937]

A NOVEL METHOD OF ARYLATION OF

[Durandetti; Sibille; Nedelec; Perichon Synthetic Communications, 1994 , vol. 24, # 2 p. 145 - 151]