Journal of fluorine chemistry

Photochemical selective fluorination of organic molecules using mercury (II) fluoride

MH Habibi, TE Mallouk

文献索引：Habibi, Mohammed H.; Mallouk, Thomas E. Journal of Fluorine Chemistry, 1991 , vol. 51, # 2 p. 291 - 294

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被引用次数: 10

摘要

Abstract Organic compounds, such as triphenylacetic acid, triphenyl ethylene, and triethyl phosphite can be selectively fluorinated in dimethylsulfoxide/HgF 2 solutions under UV- visible illumination. Product yields, determined by 19 F-NMR, are essentially quantitative for the compounds studied, and in some cases only a single fluorinated product is formed.