Organophosphorus chemistry 32. The reaction of vanillin, ortho-vanillin and piperonal with stabilized methylenetriphenylphosphoranes (Wittig reagents)

…, MM Henary, M Refat, H Mahran

文献索引：Hafez, Taghrid S.; Henary, Maged M.; Mahran, Mohamed Refat H. Phosphorus, Sulfur and Silicon and Related Elements, 1998 , vol. 143, p. 33 - 44

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被引用次数: 2

摘要

Abstract Vanillin (1) and piperonal (3) reacted with ylidenetriphenylphosphoranes 4a-f in boiling toluene following the Wittig mechanism to give the ethylenes 5a-f and 7a-f. Similarly, ethylenes 8c-f were produced when orrho-vanillin (2) was allowed to react with 4c-f. The reaction of aldehyde (2) with the P-ylides 4a, b yielded the Wittig products 8a, b and 8- methoxycoumarin (10). Triphenylphosphine oxide (TPPO, 6) was isolated and identified in ...