The Journal of Organic Chemistry

Synthesis of halogenated esters of fluorinated carboxylic acids by the regio-and stereospecific addition of acyl hypochlorites to olefins

I Tari, DD DesMarteau

文献索引：Tari, Isao; DesMarteau, Darryl D. Journal of Organic Chemistry, 1980 , vol. 45, # 7 p. 1214 - 1217

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被引用次数: 17

摘要

Addition reactions of the fluorinated acyl hypochlorites CF3CO2C1, C $ F6C02C1, n- C3F7C02C1, ClCF2C02Cl, and HCF2C02Cl with CF2= CF2 and CF2= CH2 form the respective esters in varying yields. The reactions are regiospecific with CF2= CH2. Additional reactions of CF3C02Cl with CF2= CFCl, CF2= CC12, CH2= CH2, and cis-and trans-CFH= CFH further illustrate the potential of the acyl hypochlorites for the synthesis of ...