Heterogeneous reaction of nitric acid with nitric oxide on glass surfaces under simulated atmospheric conditions

J Kleffmann, T Benter, P Wiesen

文献索引：Kleffmann, Joerg; Benter, Thorsten; Wiesen, Peter Journal of Physical Chemistry A, 2004 , vol. 108, # 27 p. 5793 - 5799

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被引用次数: 34

摘要

The heterogeneous reaction of nitric acid (HNO3) with nitric oxide (NO) on borosilicate glass surfaces was studied in a flow system at relative humidity levels in the range 21-86%. Reactant concentrations were kept closer to ambient atmospheric levels as compared to all previous studies of this reaction. Within experimental error, no formation of the proposed reaction products nitrous acid (HONO) and nitrogen dioxide (NO2) was observed. Upper ...