Stabilization of 1, 3-dipoles by. pi.-complex formation. Iron carbonyl derivatives of thio-and selenoketocarbenes

GN Schrauzer, H Kisch

文献索引：Schrauzer; Kisch Journal of the American Chemical Society, 1973 , vol. 95, p. 2501,2503,2504,2507

全文：HTML全文

被引用次数: 49

摘要

Abstract: Trihapto-1, 2-diphenylthioketocarbenehexacarbonyldiiron, the first transition metal derivative of a 1, 3-dipolar species, was obtained by the reaction of 1, 4-dimethylnickel (II) bis (cis-stilbenedithiolate) or of diphenyl-I, 2, 3-thiadiazole with iron carbonyls on heating and light irradiation. The corresponding selenoketocarbene complex was prepared analogously from diphenyl-l, 2, 3-selenodiazole. The same method was used to ...