European journal of organic chemistry

A remarkably efficient Markovnikov hydrochlorination of olefins and transformation of nitriles into imidates by use of AcCl and an alcohol

VK Yadav, KG Babu

文献索引：Yadav, Veejendra K.; Babu, K. Ganesh European Journal of Organic Chemistry, 2005 , # 2 p. 452 - 456

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被引用次数: 23

摘要

Abstract HCl generated by mixing AcCl with EtOH brings about Markovnikov hydrochlorination of olefins in excellent yields. The products are isolated in states of high purity simply by removal of the volatile components under reduced pressure. Further, nitriles are transformed into imidate hydrochlorides on similar treatment with AcCl and an alcohol. This procedure for nitrile-imidate transformation is much more efficient than that used ...