The Journal of organic chemistry

Spectral Properties and Reactivity of Diarylmethanol Radical Cations in Aqueous Solution. Evidence for Intramolecular Charge Resonance1

M Bietti, O Lanzalunga

文献索引：Bietti, Massimo; Lanzalunga, Osvaldo Journal of Organic Chemistry, 2002 , vol. 67, # 8 p. 2632 - 2638

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被引用次数: 12

摘要

Spectral properties and reactivities of ring-methoxylated diarylmethane and diarylmethanol radical cations, generated in aqueous solution by pulse and γ-radiolysis and by the one- electron chemical oxidant potassium 12-tungstocobalt (III) ate, have been studied. The radical cations display three bands in the UV, visible, and vis-NIR regions of the spectrum. The vis-NIR band is assigned to an intramolecular charge resonance interaction (CR) ...