Journal of Molecular Structure

Synthesis and multinuclear NMR investigation of some mesoionic 3-phenyl-5-imino-1, 2, 3, 4-oxatriazole imines

J Jaźwiński, O Staszewska-Krajewska

文献索引：Jazwinski, Jaroslaw; Staszewska-Krajewska, Olga Journal of Molecular Structure, 2004 , vol. 687, # 1-3 p. 23 - 33

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被引用次数: 5

摘要

Six new derivatives of mesoionic 3-phenyl-5-imino-1, 2, 3, 4-oxatriazole imine have been obtained and investigated by 1H, 13C, 14N, 15N and 17O NMR techniques. The 15N and 17O NMR studies reveal that mesoionic oxatriazoles imines exist in a cyclic,'mesoionic'form. Two stable conformers of mesoionic 3-phenyl-5-imino-1, 2, 3, 4-oxatriazole imines, E and Z, in comparable concentrations, have been detected for the first time in the solution by the ...