Ketene Acetals. XXXIV. Tetra-and Pentamethylene Ketene Acetals

SM McElvain, RE Starn Jr

文献索引：McElvain; Starn Journal of the American Chemical Society, 1955 , vol. 77, p. 4571,4577

被引用次数: 25

摘要

Ketene acetals VI11 and VIIIa with the nucleophilic center in a cyclopentane and cyclohexane ring have been prepared by the dealcoholation of the corresponding orthoesters VI1 and VIIa. These dealcoholations proceed in satisfactory yields only with sublimed aluminum t-butoxide. Methyl and t-butyl normal esters are significant reaction products and evidence is presented as to their mode of formation. Attempts to prepare the ...

5117-85-1

1-羟基环戊烷甲腈

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