Journal of the American Chemical Society

Reactions of Ethylenimines: With Ammonia and Amines

LB Clapp

文献索引：Clapp Journal of the American Chemical Society, 1948 , vol. 70, p. 184

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被引用次数: 27

摘要

Ammonia and amines' in aqueous solution react with imines to give a,@-diamines and polymeric substances. The reaction between ethylenimine and various amines to give N- substituted ethylenediamines has also been carried out under anhydrous conditions in the presence of aluminum chloride2 as a catalyst. Coleman and Callen used aqueous reactions in working up the reaction mixtures, however, which introduces some obvious ...