Reductive Transformation of V(III) Precursors into Vanadium (II) oxide Nanowires

10.1039/C8DT00848E

2018-04-14

Vanadium (II) oxide nanostructures are promising materials for supercapacitors and electrocatalysis because of their excellent electrochemical properties and high surface area. In this study, new homoleptic vanadium (III) complexes with bi-dentate O, N-chelat...

New coordination networks containing trinuclear lanthanide complexes and hexacyanometallates

10.1039/C7DT02541F

2018-04-13

Three different families of trinuclear lanthanide complexes supported by TDCI (1,3,5- tris(dimethylamino)-1,3,5-trideoxy-cis-inositol), [Ln3(TDCI)2(H2O)]6]3+, and hexacyanometallates as linkers have been synthesized and structurally characterized. The combina...

Three new types of transition metal carboranylamidinate complexes

10.1039/C8DT01064A

2018-04-13

Three new types of transition metal carboranylamidinate complexes are reported. The tetranuclear Mn(II) complexes Mn4Cl6[(o-C2B10H10)C(NiPr)(NHiPr)]2(THF)4•THF (2) was prepared by treatment of anhydrous MnCl2 with Li[(o-C2B10H10)C(NiPr)(NHiPr)] (= Li[HLiPr]) ...

Outstanding Reviewers for Dalton Transactions in 2017

10.1039/C8DT90063A

2018-04-13

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Cyclometalated iridium(III) complexes induce mitochondria-derived paraptotic cell death and inhibit tumor growth in vivo

10.1039/C8DT00783G

2018-04-13

The development of iridium complexes as potent anticancer agents have received increasing attention in recent years. In this study, four cyclometalated Ir(III) complexes with good photophysical properties and potent anticancer activity have been synthesized a...

Bond Energy, Site Preferential Occupancy and Eu2+/3+ Co-doping System Induced by Eu3+ Self-reduction in Ca10M(PO4)7 (M=Li, Na, K) Crystals

10.1039/C8DT00749G

2018-04-13

The Ca10M(PO4)7: Eu (M=Li, Na, K) phosphors have been synthesized via solid-state reaction process, their phase purity was examined by XRD patterns, Rietveld refinement confirmed the Ca10Li(PO4)7, Ca10Na(PO4)7 and Ca10K(PO4)7 are pure phase. The photoluminesc...

Effect of sulfonamidoethylenediamine substituents in RuII arene anticancer catalysts on transfer hydrogenation of coenzyme NAD+ by formate

10.1039/C8DT00438B

2018-04-13

A series of neutral pseudo-octahedral RuII sulfonamidoethylenediamine complexes [(η6-p-cym)Ru(N,N′)Cl] where N,N′ is N-(2-(R1,R2-amino)ethyl)-4-toluenesulfonamide (TsEn(R1,R2)) R1,R2 = Me,H (1); Me,Me (2); Et,H (3); benzyl,H (Bz, 4); 4-fluorobenzyl,H (4-F-Bz,...

The effect of ligand symmetry on the ratiometric luminescence characteristics of lanthanides

10.1039/C8DT00898A

2018-04-13

This work demonstrated that the ligand symmetry of europium(III) complexes controls the ratiometric luminescence characteristics of the lanthanide. Nona-coordinated europium(III) complexes having unsymmetrical β-diketonate ligands (CS) exhibit distinctive rat...

Schiff-base -Ate Derivatives with Main Group Metals: Generation of a Tripodal Aluminate Metalloligand

10.1039/C8DT00835C

2018-04-12

New heterobimetallic aluminates with well-defined structures bearing bidentate Schiff bases as ligands have been prepared. The ligands studied are PhO-CH=N-Ar (Ar = C6H5 (La), 2,6-iPr-C6H3 (Lb)), with and without donor substituents in ortho position of the ar...

A Novel Metallogel Based Approach to Synthesize (Mn, Cu) Doped ZnS Quantum Dots and Labelling of MCF-7 Cancer Cells.

10.1039/C7DT03864J

2018-04-12

The present work aims to formulate a common synthetic strategy for preparing quantum dots (QDs) in a greener way by using the combination of popular methods, viz. colloidal method with suitable capping agent, low molecular weight gel based synthesis. Pyridine...