麝香结构式
|
常用名 | 麝香 | 英文名 | 1,1,3,3,5-pentamethyl-4,6-dinitroindane |
|---|---|---|---|---|
| CAS号 | 116-66-5 | 分子量 | 278.30400 | |
| 密度 | 1.182g/cm3 | 沸点 | 351.1ºC at 760mmHg | |
| 分子式 | C14H18N2O4 | 熔点 | N/A | |
| MSDS | 美版 | 闪点 | 145.3ºC | |
| 符号 |
GHS02, GHS07 |
信号词 | Danger |
麝香用途是贵重药材。可用于高级香水中。一般香精中常用合成麝香代替。 用作高档香料的定香剂 |
| 中文名 | 麝香 |
|---|---|
| 英文名 | 1,1,3,3,5-pentamethyl-4,6-dinitro-2H-indene |
| 中文别名 | 2,3-二氢-1,1,3,3,5-五甲基-4,6-二硝基-1H-茚 | 1,1,3,3,5-五甲基-4,6-二硝基茚 | 1,1,3,3,5-五甲基-4,6-二硝基茚满 |
| 英文别名 | 更多 |
| 密度 | 1.182g/cm3 |
|---|---|
| 沸点 | 351.1ºC at 760mmHg |
| 分子式 | C14H18N2O4 |
| 分子量 | 278.30400 |
| 闪点 | 145.3ºC |
| 精确质量 | 278.12700 |
| PSA | 91.64000 |
| LogP | 4.81670 |
| 蒸汽压 | 8.49E-05mmHg at 25°C |
| 折射率 | 1.55 |
| 储存条件 | 2-8°C |
| 稳定性 | 棕黄色至深褐色的卵圆状物，囊内是胶状分泌物。有强烈持久的特殊动物香。 |
| 分子结构 | 1、 摩尔折射率：74.98 2、 摩尔体积（cm3/mol）：235.3 3、 等张比容（90.2K）：608.1 4、 表面张力（dyne/cm）：44.6 5、 极化率（10-24cm3）：29.72 |
| 计算化学 | 1.疏水参数计算参考值（XlogP）:4.5 2.氢键供体数量:0 3.氢键受体数量:4 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积91.6 7.重原子数量:20 8.表面电荷:0 9.复杂度:435 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1 |
| 更多 | 1.性状：一种动物性香料。是3岁以上的雄麝鹿香囊中的干燥分泌物。干燥后是红棕色至暗棕色的粒状物质。有不愉快的原始气味，但高度稀释后有独特的香气。 |
| 符号 |
GHS02, GHS07 |
|---|---|
| 信号词 | Danger |
| 危害声明 | H225-H302-H312-H319-H332 |
| 警示性声明 | P210-P280-P305 + P351 + P338 |
| 个人防护装备 | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| 危害码 (欧洲) | F: Flammable;Xn: Harmful; |
| 风险声明 (欧洲) | 11-20/21/22-36 |
| 安全声明 (欧洲) | S16;S36/S37 |
| 危险品运输编码 | UN 1648 3/PG 2 |
| 海关编码 | 2914700090 |
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~%
麝香 116-66-5 |
| 文献：Helvetica Chimica Acta, , vol. 15, p. 592,594 Rev. Marques Parf. Savonn., , vol. 12, p. 325 Helvetica Chimica Acta, , vol. 38, p. 1263,1265 US1892128 , ; FR710295 , ; |
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~%
麝香 116-66-5 |
| 文献：Helvetica Chimica Acta, , vol. 15, p. 592,594 Rev. Marques Parf. Savonn., , vol. 12, p. 325 Helvetica Chimica Acta, , vol. 38, p. 1263,1265 |
|
~%
麝香 116-66-5 |
| 文献：Helvetica Chimica Acta, , vol. 15, p. 592,594 Rev. Marques Parf. Savonn., , vol. 12, p. 325 |
| 麝香上游产品 3 | |
|---|---|
| 麝香下游产品 0 | |
| 海关编码 | 2914700090 |
|---|---|
| 中文概述 | 2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 丙酮报明包装 |
| Summary | HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0% |
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Simultaneous congener-specific determination of selected organochlorine compounds and nitro musks in human whole blood samples by solid-phase extraction and capillary gas chromatography with electron capture detection.
J. Anal. Toxicol. 29(2) , 110-7, (2005) Chlororganic compounds like pesticides or polychlorinated biphenyls (PCB) and nitro musks are environmental contaminants, which remain public health concerns because of their persistence in humans and... |
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Determination of polycyclic and nitro musks in environmental water samples by means of microextraction by packed sorbents coupled to large volume injection-gas chromatography-mass spectrometry analysis.
Anal. Chim. Acta 773 , 68-75, (2013) In this work the development and validation of a new procedure for the simultaneous determination of 9 nitro and polycyclic musk compounds: musk ambrette (MA), musk ketone (MK), musk mosken (MM), cele... |
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High-sensitivity analysis of six synthetic musks by ultra-performance liquid chromatography-atmospheric pressure photoionization-tandem mass spectrometry.
Anal. Chem. 83(12) , 4955-61, (2011) The occurrence and potential toxicity of synthetic musks in environmental media have aroused concerns for the impacts of these chemicals on ecosystems and human health. Here, we present the first meth... |
| Nitromusl moskene |
| Moskene |
| musk,oscene |
| 1H-Indene,2,3-dihydro-1,1,3,3,5-pentamethyl-4,6-dinitro |
| EINECS 204-149-4 |
| Musk moskene |
| 1,1,3,3,5-Pentamethyl-4,6-dinitroindane |
| MFCD00021242 |
| 4,6-DINITRO-1,1,3,3,5-PENTAMETHYLINDANE |
| Musk moskene solution |
| 1,1,3,3,5-pentamethyl-4,6-dinitroindan |
