哒嗪硫磷
哒嗪硫磷用途
具有触杀、胃毒作用的杀虫剂，对粮油、蔬菜、果树、森林等植物的多种主要害虫均有良好防效
【用途二】
用于防治水稻二化螟、三化螟、叶蝉、稻飞虱、棉红蜘蛛、花生蚜虫等害虫
【用途三】
高效、低毒、低残留、广谱性有机磷杀虫剂。 具有触杀和胃毒作用，无内吸作用。对多种刺吸式口器和咀嚼式害虫有较好防治效果。用于防治水稻螟虫及稻苞虫、稻纵卷叶螟、稻飞虱、稻飞虱、稻叶蝉、稻蓟马和棉花红蜘蛛及棉蚜、红铃虫、棉铃虫等。 对蔬菜、小麦、油料、杂粮、果树、森林等作物多种害虫也有良好的防治效果。防治棉花红蜘蛛2.2～3g有效成分/100m2，防治水稻二化螟6～9g有效成分/100m2。
【用途四】
一种有机磷杀虫、杀螨剂。具有胃毒、触杀作用，兼有杀卵作用。用于防治水稻二化螟、三化螟、叶蝉、稻飞虱、稻苞虫、棉红蜘蛛、花生蚜虫等害虫。对稻卷叶螟和稻飞虱的防效较差。不能与碱性农药混用，不能与2，4-滴除草剂同时使用或两药使用的间隔期太短，否则产生药害。
哒嗪硫磷名称
[ CAS 号 ]:
119-12-0
[ 中文名 ]:
哒嗪硫磷
[ 英文名 ]:
PYRIDAFENTHION
[中文别名 ]:
[英文别名 ]:
- PYRIDAPHENTHION
- American Cyanamid 12503
- MFCD00145189
- EINECS 204-298-5
- PYRIDAFENTHION
哒嗪硫磷物理化学性质
[ 密度 ]:
1.3±0.1 g/cm3
[ 沸点 ]:
416.2±28.0 °C at 760 mmHg
[ 分子式 ]:
C14H17N2O4PS
[ 分子量 ]:
340.335
[ 闪点 ]:
205.5±24.0 °C
[ 精确质量 ]:
340.064667
[ PSA ]:
104.48000
[ LogP ]:
3.08
[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C
[ 折射率 ]:
1.589
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
哒嗪硫磷MSDS
哒嗪硫磷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TF2275000
- CHEMICAL NAME :
- Phosphorothioic acid, O,O-diethyl ester, O-ester with 6-hydroxy-2-phenyl-3(2H)pyridazinone
- CAS REGISTRY NUMBER :
- 119-12-0
- BEILSTEIN REFERENCE NO. :
- 0302741
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 17
- MOLECULAR FORMULA :
- C14-H17-N2-O4-P-S
- MOLECULAR WEIGHT :
- 340.36
- WISWESSER LINE NOTATION :
- T6NNVJ BR& FOPS&O2&O2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 424 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 37,1621,1986
- TYPE OF TEST :
- LC50 - Lethal concentration, 50 percent kill
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1100 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,285,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2100 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C223,1991
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 105 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 305 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 237 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Gastrointestinal - hypermotility, diarrhea
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 53(11),66,1988
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 660 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 64 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- 28ZEAL "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969 Volume(issue)/page/year: 4,170,1969
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 370 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- >12 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- >20 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 4800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 513 mg/kg
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Sense Organs and Special Senses (Eye) - effect, not otherwise specified Gastrointestinal - hypermotility, diarrhea
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 53(11),66,1988
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - quail
- DOSE/DURATION :
- 68400 ug/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- JPIFAN Japan Pesticide Information. (Japan Plant Protection Assoc., 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) No.1-61, 1969-92. For publisher information, see AGJAEP. Volume(issue)/page/year: (33),9,1977 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 201 mg/kg/48W-I
- TOXIC EFFECTS :
- Kidney, Ureter, Bladder - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases Biochemical - Metabolism (Intermediary) - effect on mitochondrial function
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 53(11),66,1988
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Mammal - species unspecified
- DOSE/DURATION :
- 15 gm/kg/30D-I
- TOXIC EFFECTS :
- Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 53(11),66,1988
哒嗪硫磷安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302 + H332
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ 危害码 (欧洲) ]:
F: Flammable;Xi: Irritant;
[ 风险声明 (欧洲) ]:
R11
[ 安全声明 (欧洲) ]:
S26
[ 危险品运输编码 ]:
2783
[ RTECS号 ]:
TF2275000
[ 包装等级 ]:
II
[ 危险类别 ]:
6.1(a)
[ 海关编码 ]:
2933990011
哒嗪硫磷制备
1.重氮化 将苯胺用亚硝酸钠、盐酸得氮化，配比为1：1.01：2.3 (mol)，亚硝酸钠配制成35%～40%水溶液， 滴加温度为5℃以下,制得重氮盐。
2.还原 重氮盐与过量亚硫酸钠反应，还原成苯肼。配比为1.0:2.2 (以苯胺计）。盐酸中和前反应温度控制在70℃，时间30min；加盐酸调节Ph值到6～7，升温回流0.5h。
缩合 顺丁烯二酸酐与苯肼（常用其盐酸水溶液）反应制得哒嗪酮。 苯肼与顺酐的投料比为1：1 （按苯胺计）， 反应温度100～109℃，时间4h，负压操作。
哒嗪硫磷的合成 在水相中以液碱和纯碱为脱酸剂， 以三四胺为催化剂， 反应温度65～70℃， O， O-二基硫代磷酰氯与哒嗪酮、液碱的配比为1：1.1:0.9， 终点控制pH值为8。
以苯胺计总收率达70%左右。
3.缩合顺丁烯二酸酐与苯肼（常用其盐酸盐水溶液）反应制得哒嗪酮。苯肼与顺酐的投料比为1∶1（按苯胺计），反应温度100～109℃，时间4犺，负压操作。
4.哒嗪硫磷的合成在水相中以液碱和纯碱为脱酸剂，以三甲胺为催化剂，反应温度65～70℃，犗犗二乙基硫代磷酰氯与哒嗪酮、液碱的配比为1∶1.1∶0.9，终点控制狆犎值为8。
哒嗪硫磷海关
[ 海关编码 ]: 2933990011
[ 中文概述 ]:
2933990011 抑芽丹,三唑磷,虫线磷,喹硫磷,唑啶草酮等〔包括哒嗪硫磷,亚胺硫磷,氯亚胺硫磷,保棉磷,益棉磷,威菌磷〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期
[ 监管条件 ]: S.进出口农药登记证明
[ Summary ]:
2933990011 o,o-diethyl o-quinoxalin-2-yl phosphorothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%
哒嗪硫磷文献
Nihon Eiseigaku Zasshi. 39(5) , 795-806, (1984)
[Effect of ofunack on the tentative exploratory activity of white rats].
Gig. Sanit. (8) , 80-2, (1987)
[Substantiation of hygienic standardization of ofunak in reservoir water].
Gig. Sanit. (11) , 66-8, (1988)
推荐生产厂家/供应商：
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区域：上海市普陀区
价格：
联系人：化源网
产品详情：哒嗪硫磷农药纯度标准物质
公司名：上海吉至生化科技有限公司
区域：上海市奉贤区
价格：
￥198.0/1ml
联系人：刘佳
产品详情：哒嗪硫磷农药纯度标准物质
公司名：上海源溪生物科技有限公司
区域：上海市浦东新区
价格：
￥需询单/1g
联系人：赖经理
产品详情：Pyridafenthion
公司名：上海阿拉丁生化科技股份有限公司
区域：上海市浦东新区
价格：
￥1350.0/100mg
￥需询单/1g
￥需询单/1g
￥需询单/1g
联系人：阿拉丁
产品详情：哒嗪硫磷农药纯度标准物质
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相关化合物
【哒嗪硫磷】化源网提供哒嗪硫磷CAS号119-12-0，哒嗪硫磷MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询哒嗪硫磷上化源网，专业又轻松。>>电脑版：哒嗪硫磷
标题：哒嗪硫磷_MSDS_用途_密度_哒嗪硫磷CAS号【119-12-0】_化源网 地址：https://www.chemsrc.com/amp/cas/119-12-0_584960.html