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(R)-(-)-仲丁醇

(R)-(-)-仲丁醇用途

(R)-(-)-2-Butanol 是由雌性白色甲虫 (Dasylepida ishigakiensis) 释放的,用来吸引雄性。(R)-(-)-2-Butanol 是药物合成的中间体。

(R)-(-)-仲丁醇名称

[ CAS 号 ]:
14898-79-4

[ 中文名 ]:
发酵丁醇

[ 英文名 ]:
(R)-(-)-2-Butanol

[中文别名 ]:

[英文别名 ]:

L-Proline, 1-methyl-, hydrate (1:1)
(R)-(-)-sec-Butanol
R-(-)-2-Butanol
(R)-(-)-sec-Butyl Alcohol
1-Methyl-L-proline hydrate (1:1)
MFCD00064280
(R)-(-)-2-Butanol
EINECS 238-967-8

(R)-(-)-仲丁醇生物活性

[ 描述 ]:

(R)-(-)-2-Butanol 是由雌性白色甲虫 (Dasylepida ishigakiensis) 释放的,用来吸引雄性。(R)-(-)-2-Butanol 是药物合成的中间体。

[ 相关类别 ]:

信号通路 >> 其他 >> 其他

研究领域 >> 代谢疾病

[参考文献]

[1]. N Fujiwara-Tsujii, et al. Age-dependent changes in the ratio of (R)- and (S)-2-butanol released by virgin females of Dasylepida ishigakiensis (Coleoptera: Scarabaeidae). Bull Entomol Res. 2012 Dec;102(6):730-6.

[2]. Aram Hong, et al. Induced Circular Dichroism of Jet-Cooled Phenol Complexes with ( R)-(-)-2-Butanol. J Phys Chem A. 2019 Oct 17;123(41):8913-8920.

(R)-(-)-仲丁醇物理化学性质

[ 密度 ]:
0.807

[ 沸点 ]:
99-100ºC

[ 熔点 ]:
-114ºC

[ 分子式 ]:
C₄H₁₀O

[ 分子量 ]:
147.172

[ 闪点 ]:
26ºC

[ 精确质量 ]:
147.089539

[ PSA ]:
20.23000

[ LogP ]:
0.77720

[ 外观性状 ]:
透明无色液体强烈的,甜的气味

[ 蒸汽压 ]:
25.2mmHg at 25°C

[ 折射率 ]:
1.396-1.398

[ 储存条件 ]:
2~8℃

[ 水溶解性 ]:
水溶性：可溶；混溶：乙醚,醇

(R)-(-)-仲丁醇MSDS

(R)-(-)-仲丁醇安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H319-H335-H335 + H336-H336

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R10;R36/37;R67

[ 安全声明 (欧洲) ]:
S13-S24/25-S26-S7/9

[ 危险品运输编码 ]:
UN 1120

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3.0

[ 海关编码 ]:
2905199090

(R)-(-)-仲丁醇合成路线

(R)-(-)-仲丁醇上下游产品

(R)-(-)-仲丁醇上游产品

(R)-(-)-仲丁醇下游产品

(R)-(-)-仲丁醇海关

[ 海关编码 ]: 2905199090

[ 中文概述 ]:
2905199090. 其他饱和一元醇. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2905199090. saturated monohydric alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

(R)-(-)-仲丁醇文献

The substrate binding cavity of particulate methane monooxygenase from Methylosinus trichosporium OB3b expresses high enantioselectivity for n-butane and n-pentane oxidation to 2-alcohol.

Biotechnol. Lett. 33(11) , 2241-6, (2011)

The particulate methane monooxygenase (pMMO) of Methylosinus trichosporium OB3b oxidized n-butane and n-pentane and mainly produced (R)-2-butanol and (R)-2-pentanol that comprised 78 and 89% of the pr...

Human phosphoglycerate dehydrogenase produces the oncometabolite D-2-hydroxyglutarate.

ACS Chem. Biol. 10(2) , 510-6, (2015)

Human d-3-phosphoglycerate dehydrogenase (PHGDH), the first enzyme in the serine biosynthetic pathway, is genomically amplified in tumors including breast cancer and melanoma. In PHGDH-amplified cance...

Interplay of metalloligand and organic ligand to tune micropores within isostructural mixed-metal organic frameworks (M'MOFs) for their highly selective separation of chiral and achiral small molecules.

J. Am. Chem. Soc. 134(20) , 8703-10, (2012)

Four porous isostructural mixed-metal-organic frameworks (M'MOFs) have been synthesized and structurally characterized. The pores within these M'MOFs are systematically tuned by the interplay of both ...

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